Novak returns to The Boodles tournament, the traditional Wimbledon warm-up event at Stoke Park in Buckinghamshire (June 23-27).
Novak will bid to become the first player in history to capture four successive Barclays ATP World Tour Finals singles titles.
No.8 seed Stan Wawrinka denied Novak career Grand Slam dream with a 4-6, 6-4, 6-3, 6-4 victory in Roland Garros final on Sunday.
The final is set and this year French Open will have a first time winner. Nole meets Stan Wawrinka (SUI, 8) on Sunday.
Novak beat nine-time French Open winner Rafael Nadal 7-5, 6-3, 6-1 in the most eagerly anticipated Grand Slam quarter-final on Wednesday.
The top seed advanced into the Roland Garros last eight with a 6-1, 6-2, 6-3 triumph over Richard Gasquet (FRA, 20) in two hours.
Top seed defeated rising Australian teenager Thanasi Kokkinakis in straight sets to reach the fourth round of the French Open for a ninth time.
Novak beat 55th-ranked Gilles Muller of Luxemburg 6-1, 6-4, 6-4 for a place in the third round of the 2015 Roland Garros.
Novak began his quest for a first Roland Garros crown with a 6-2, 7-5, 6-2 victory over 87th-ranked Jarkko Nieminen on Tuesday.
The second Grand Slam of the season, the Roland Garros, is taking place in Paris, from May 24 to June 7, 2015.