World no.1 arrived in Madrid with a 28-2 record on the season. The 2011 champion will open campaign against either Borna Coric (CRO) or Nicolas Almagro (ESP).
Novak is a top seed and has a first-round BYE. He will open his campaign against world no.55 Jiri Vesely (CZE).
World no.1 and five-time champion is a top seed and has a first round BYE. He will open title defence against Kyle Edmund.
Novak will begin title defence in Indian Wells in the second round against Bjorn Fratangelo (USA, Q).
World no.1 Novak Djokovic returns to the tennis court on Friday, as Serbia hosts Kazakhstan in the Davis Cup first round tie in Belgrade.
Novak is making his tenth appearance at the Dubai Duty Free Tennis Championships, aiming for his fifth crown.
Top seed and five-time defending champion will open campaign in his 12th Australian Open appearance against world no.51, Hyeon Chung.
Novak is no.1 seed and will open his Qatar ExxonMobil Open campaign against German qualifier Dustin Brown (ATP #118).
The world’s biggest indoor tournament begins on Sunday, November 15, at the O2 Arena in London, and will be played until November 22.
Singles draw was made for the 2015 BNP Paribas Masters in Paris on Friday.