Novak will open against Albert-Ramos-Vinolas, before Troicki plays Pablo Carreno Busta on Day 1.
Nole is no.1 seed and will open his Abierto Mexicano Telcel campaign against world no.65 Martin Klizan.
Viktor Troicki will open the first round for Serbia against Karen Kachanov before Novak faces Daniil Medvedev on Day 1.
The 12-time Grand Slam titlist headlines Serbia’s team nominations and will be joined in the line-up by Troicki, Lajovic and Zimonjic.
Second seed and six-time defending champion will open campaign in his 13th Australian Open appearance against world no.40 Fernando Verdasco.
Novak is no.2 seed and will open his title defence campaign against Jan-Lennard Struff (ATP #63). It will be their first career meeting.
The world’s biggest indoor tournament begins on Sunday, November 13, at the O2 Arena in London.
Nole is no.1 seed and will open his quest for a fifth title in Bercy in the second round against world no.34 Gilles Muller from Luxembourg.
Serbia will face Russia in a home tie in the first round on 3-5 February 2017.
Top seed and defending champion will open campaign in his 12th US Open appearance against Jerzy Janowicz (Poland).